多邊框

使用大綱：

.div1{
  border: 3px solid black; 
  outline: 6px solid blue;
  width: 100px;
  height: 100px;
  margin: 20px;
}

使用 box-shadow：

.div2{
  border: 5px solid green; 
  box-shadow: 0px 0px 0px 4px #000;
  width: 100px;
  height: 100px;
  margin: 20px;
}

使用偽元素：

.div3 {
  position: relative;
  border: 5px solid #000;
  width: 100px;
  height: 100px;
  margin: 20px;
}
.div3:before {
  content: " ";
  position: absolute;
  border: 5px solid blue;
  z-index: -1;
  top: 5px;
  left: 5px;
  right: 5px;
  bottom: 5px;
}

http://jsfiddle.net/MadalinaTn/bvqpcohm/2/